Interconversion of Highly Entangled Polyhedra into Concave Polyhedra by Nitrate-Induced Ternary Coordination,Angewandte Chemie International Edition

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Interconversion of Highly Entangled Polyhedra into Concave Polyhedra by Nitrate-Induced Ternary Coordination
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-05-03 , DOI: 10.1002/anie.202303714
Yuya Domoto ₁ , Masahiro Abe _{2,

3} , Georgi R Genov ₂ , Zhengsu Yu ₂ , Makoto Fujita _{2,

4}

Affiliation

An anion-exchange-triggered interconversion of entangled (Ag₃L₂)_n polyhedra has resulted in a formal metal insertion into their main frameworks to give a new series of concave polyhedra, supported by a heteroleptic ternary coordination mode with cooperating metal–acetylene interactions. This finding provides clues toward the skeletal editing of large, complex 3D architectures.

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