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Preparation, Characterization, and Mechanistic Considerations for 1,1,1-Tri(thioacetyl)ethane and 1,1-Di(thioacetyl)ethene
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2023-05-03 , DOI: 10.1021/acs.joc.3c00377 Erik S Goebel 1 , Matthew J Turcotte 1 , Madeleine J Henley 1 , Victor G Young 1 , George Barany 1
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2023-05-03 , DOI: 10.1021/acs.joc.3c00377 Erik S Goebel 1 , Matthew J Turcotte 1 , Madeleine J Henley 1 , Victor G Young 1 , George Barany 1
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Two new compounds, 1,1,1-tri(thioacetyl)ethane and 1,1-di(thioacetyl)ethene, arose during reactions of acetyl methoxy(thiocarbonyl) sulfide with potassium methyl xanthate. Relevant mechanisms were elucidated, which in turn suggested novel streamlined routes to these same compounds. Several further transformations of the title compounds were demonstrated, suggesting their potential synthetic utility.
中文翻译：
1,1,1-三（硫代乙酰基）乙烷和 1,1-二（硫代乙酰基）乙烯的制备、表征和机理考虑
在乙酰甲氧基（硫代羰基）硫化物与甲基黄原酸钾的反应过程中产生了两种新化合物，1,1,1-三（硫代乙酰基）乙烷和 1,1-二（硫代乙酰基）乙烯。阐明了相关机制，这反过来又为这些相同化合物提出了新的简化路线。证明了标题化合物的几种进一步转化，表明它们具有潜在的合成用途。
更新日期：2023-05-03
中文翻译：
1,1,1-三（硫代乙酰基）乙烷和 1,1-二（硫代乙酰基）乙烯的制备、表征和机理考虑
在乙酰甲氧基（硫代羰基）硫化物与甲基黄原酸钾的反应过程中产生了两种新化合物，1,1,1-三（硫代乙酰基）乙烷和 1,1-二（硫代乙酰基）乙烯。阐明了相关机制，这反过来又为这些相同化合物提出了新的简化路线。证明了标题化合物的几种进一步转化，表明它们具有潜在的合成用途。
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