Spinel ferrite catalysts (SFCs) have demonstrated significant benefits as excellent materials for the sustainable production of high-value chemicals from CO₂ hydrogenation thanks to their flexible structure, tunable composition, and thermal stability. They can promote the activation, adsorption, and reactivity of CO₂ with high conversion efficiencies and stable performances. These have triggered the exponentially growing attention they have received in the last few years. Here, current developments in catalytic CO₂ hydrogenation to olefins, alcohols, aromatics, and other liquid hydrocarbons are discussed in terms of fabrication, modification strategies, and structure-performance relationships under various categories of SFCs, namely Fe₃O₄ (magnetite)-based, transition-metal-based, alkaline-earth metal-based, and Al-based SFCs. Furthermore, the review reveals key performance-influencing factors and provides insights into selectivity control mechanisms during the SFC-promoted CO₂ hydrogenation reaction. In the end, current underlying challenges and recommendations to motivate further design of more high-performance SFCs with long lifespans for CO₂ hydrogenation are provided.

尖晶石铁氧体催化剂 (SFC)凭借其灵活的结构、可调的组成和热稳定性，作为用于通过 CO ₂加氢可持续生产高价值化学品的优秀材料，已显示出显着优势。_{它们可以促进CO 2}的活化、吸附和反应，转化效率高，性能稳定。这些引发了他们在过去几年中受到的成倍增长的关注。在此，从各种 SFC（即 Fe 3）的制造、改性策略和结构-性能关系方面讨论了_CO 2 催化加氢制烯烃、醇类、芳烃和其他液态烃的当前_发展O ₄ (磁铁矿)基、过渡金属基、碱土金属基和Al基SFC。此外，该综述揭示了关键的性能影响因素，并提供了对 SFC 促进的 CO ₂加氢反应过程中选择性控制机制的见解。最后，提供了当前潜在的挑战和建议，以推动进一步设计更多具有长寿命的高性能 SFC 用于 CO _2加氢。