Transition metal phosphates have been considered as a kind of promising electrocatalysts towards oxygen evolution reaction (OER), however, the unsatisfactory OER activity and tedious preparation process greatly restrict their further application. Herein, we report a novel microwave assistant strategy to fabricate graphene supported Fe_xNi_2−xP₄O₁₂ (Fe_xNi_2−xP₄O₁₂/RGO) hybrids as OER electrocatalyst. In alkaline solution, the optimized Fe_xNi_2−xP₄O₁₂/RGO merely needs low overpotential of 277, 340 and 380 mV to achieve 100, 500 and 1000 mA cm⁻², respectively. Moreover, the electrolytic cell assembled by Fe_xNi_2−xP₄O₁₂/RGO and Pt/C only requires voltage of 1.549, 1.678 and 1.773 V to generate 100, 500 and 1000 mA cm⁻², respectively, outperforming the electrolytic cell assembled by IrO₂ and Pt/C. Durability test at 100 mA cm⁻² for 100 h displays no obvious degradation of activity, confirming its outstanding stability. The strategy presented in this work affords a new avenue to fabricate high performance electrocatalysts.

过渡金属磷酸盐被认为是一种很有前途的析氧反应（OER）电催化剂，然而，不理想的OER活性和繁琐的制备过程极大地限制了它们的进一步应用。在此，我们报告了一种新型微波辅助策略来制备石墨烯负载的 Fe _x Ni _2−x P ₄ O ₁₂ (Fe _x Ni _2−x P ₄ O ₁₂ /RGO) 杂化物作为 OER 电催化剂。在碱性溶液中，优化的 Fe _x Ni _2−x P ₄ O ₁₂/RGO 仅需要 277、340 和 380 mV 的低过电势即可分别达到 100、500 和 1000 mA cm ^-2。_{此外，由 Fe x} Ni _2−x P ₄ O ₁₂ /RGO 和 Pt/C组装的电解池仅需要 1.549、1.678 和 1.773 V 的电压即可分别产生 100、500 和 1000 mA cm ^-2，优于电解池由 IrO ₂和 Pt/C 组装而成的电池。^{在 100 mA cm -2}下持续 100 小时的耐久性测试显示活性没有明显下降，证实了其出色的稳定性。这项工作中提出的策略为制造高性能电催化剂提供了一条新途径。