Energetic ionic compounds have attracted substantial research interest over the past decade due to their relatively low sensitivities compared to the corresponding covalent compounds. However, by far, the synthesis of energetic ionic molecules is mostly limited to the designing of anionic moieties. Herein, we report a practical synthesis of 3,4-diamino-6-azido-1H-pyrazolo[4,3-c]pyridin-5-ium energetic ionic compounds which show good detonation performances and low sensitivities. This synthetic strategy could be employed for the synthesis of fused pyridinyl azides, which highlights its importance in the field of heterocyclic chemistry.

中文翻译：

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3,4-二氨基-6-叠氮基-1H-吡唑并[4,3-c]吡啶-5-ium高能离子化合物的实用合成

由于与相应的共价化合物相比，高能离子化合物的灵敏度相对较低，因此在过去十年中引起了广泛的研究兴趣。然而，到目前为止，高能离子分子的合成主要局限于阴离子部分的设计。在此，我们报告了 3,4-二氨基-6-叠氮基-1 H-吡唑并[4,3- c ]吡啶-5-ium 高能离子化合物的实际合成，该化合物具有良好的爆轰性能和低灵敏度。该合成策略可用于稠合吡啶基叠氮化物的合成，突出了其在杂环化学领域的重要性。