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Protic amino-2-propanol hydrochloride-based deep eutectic solvents with multiple hydrogen bond sites for efficient capture of NH3
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2023-04-27 , DOI: 10.1016/j.ijhydene.2023.04.112
Pingping Shao , Ruoya Wang , Tianxiang Zhao , Chun Zhu

The ammonia (NH3) emitting into the atmosphere during the industrial process of synthesizing ammonia not only constitutes serious air pollution, but also causes a waste of ammonia resources. Therefore, there is an urgent need to develop efficient ammonia capture technology. In this work, we report an efficient capture of NH3 by protic amino-2-propanol hydrochloride-based deep eutectic solvents (DESs). These DESs with multiple hydrogen bond sites exhibit remarkable NH3 uptake with up to 0.244 g NH3 per g DES at 293 K and 1 bar and good recyclability. Further mechanism study suggested that the introduction of hydrogen bond donors with rich hydroxyl groups provides a large number of hydrogen bond sites to achieve efficient absorption of NH3 through the intermolecular hydrogen bonds interaction. This research has obtained an alternative absorber for the capture of NH3, and it also provides ideas for the design of high-efficiency NH3 deep eutectic solvents absorbent.



中文翻译:

基于质子氨基-2-丙醇盐酸盐的低共熔溶剂,具有多个氢键位点,可有效捕获 NH3

合成氨工业过程中向大气排放的氨(NH 3 )不仅构成严重的空气污染,而且造成氨资源的浪费。因此,迫切需要开发高效的氨捕获技术。在这项工作中,我们报告了通过质子氨基-2-丙醇盐酸盐基低共熔溶剂(DES)有效捕获 NH 3 。这些具有多个氢键位点的 DES 表现出显着的 NH 3吸收能力,在 293 K 和 1 bar 下每克 DES 吸收高达 0.244 g NH 3 ,并且具有良好的可回收性进一步的机理研究表明,引入具有丰富羟基的氢键供体提供了大量的氢键位点,通过分子间氢键相互作用实现NH 3的高效吸收。本研究获得了一种捕获NH 3的替代吸收剂,也为高效NH 3低共熔溶剂吸收剂的设计提供了思路。

更新日期:2023-04-27
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