Matched Ligands for Small, Stable Colloidal Nanoparticles of Copper, Cuprous Oxide and Cuprous Sulfide,Chemistry - A European Journal

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Matched Ligands for Small, Stable Colloidal Nanoparticles of Copper, Cuprous Oxide and Cuprous Sulfide
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-04-20 , DOI: 10.1002/chem.202300228
Bradley E Cowie ₁ , Lisa Häfele ₁ , Andreas Phanopoulos _{1,

2} , Said A Said ₁ , Ja Kyung Lee ₂ , Anna Regoutz ₃ , Milo S P Shaffer ₂ , Charlotte K Williams ₁

Affiliation

Ultra-small and stable colloidal nanoparticles of copper, cuprous oxide and cuprous sulfide were synthesized exploiting the organometallic chemistry of copper mesityl. Sub-stoichiometric quantities of X-type carboxylate and di(thio)carboxylate ligands were used to produce colloidal nanoparticles; the nature of the ligand influences both the nanoparticle solubility and stability.

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