Visible-light-mediated dearomatisation of pyrroles is a powerful strategy for the synthesis of pharmaceuticals and bioactive compounds. Herein we present the chemiluminescent reaction between pyrrole metalated-Ir(III) complex [Ir(K²_C,N-DPP)(H)(Cl)(PPh₃)₂] (1) and singlet oxygen to form a ketoamide complex [Ir(K²_C,N-ketoamide)(H)(Cl)(PPh₃)₂] (2). Complex 2 are fully characterized by NMR and single crystal X-ray diffraction analysis. The reaction mechanism of metalated pyrrole-singlet reaction upon irradiation is studied by experiment and DFT calculations.

中文翻译：

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金属化吡咯-单线态氧化学发光反应机理

可见光介导的吡咯脱芳构化是合成药物和生物活性化合物的有力策略。在此，我们展示了吡咯金属化 Ir(III) 络合物 [Ir( K ² _{C, N} -DPP)(H)(Cl)(PPh ₃ ) ₂ ] ( 1 ) 和单线态氧之间的化学发光反应，形成酮酰胺络合物 [ Ir(K ² _{C, N-}酮酰胺)(H)(Cl)(PPh ₃ ) ₂ ] ( 2 )。复杂2通过 NMR 和单晶 X 射线衍射分析完全表征。通过实验和DFT计算研究了金属化吡咯单线态反应在辐照下的反应机理。