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Multi-layer 3D Chirality and Double-Helical Assembly in a Copper Nanocluster with a Triple-Helical Cu15 Core
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-04-13 , DOI: 10.1002/anie.202302595
Guanglei Dong 1 , Zhonghua Pan 2 , Baoliang Han 3 , Yunwen Tao 4 , Xin Chen 5 , Geng-Geng Luo 1, 6 , Panpan Sun 3 , Cunfa Sun 1 , Di Sun 3
Affiliation  

An atom-precise copper nanocluster containing a chiral triple-stranded helical core has been synthesized and structurally characterized. The nanocluster shows unique multi-layer 3D chirality and assembles into double-helical secondary structure with emergent distinct optical and catalytic properties.

中文翻译:

具有三螺旋 Cu15 核心的铜纳米团簇中的多层三维手性和双螺旋组装

已合成并在结构上表征了包含手性三股螺旋核的原子精确铜纳米团簇。纳米团簇显示出独特的多层 3D 手性,并组装成双螺旋二级结构,具有明显的光学和催化特性。
更新日期:2023-04-13
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