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Understanding MOF Flexibility: An Analysis Focused on Pillared Layer MOFs as a Model System
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-04-13 , DOI: 10.1002/anie.202218076 Irena Senkovska 1 , Volodymyr Bon 1 , Leila Abylgazina 1 , Matthias Mendt 2 , Jan Berger 3 , Gregor Kieslich 3 , Petko Petkov 4 , Jhonatan Luiz Fiorio 5 , Jan-Ole Joswig 5 , Thomas Heine 5, 6, 7 , Larissa Schaper 8 , Christopher Bachetzky 9 , Rochus Schmid 8 , Roland A Fischer 3 , Andreas Pöppl 2 , Eike Brunner 9 , Stefan Kaskel 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-04-13 , DOI: 10.1002/anie.202218076 Irena Senkovska 1 , Volodymyr Bon 1 , Leila Abylgazina 1 , Matthias Mendt 2 , Jan Berger 3 , Gregor Kieslich 3 , Petko Petkov 4 , Jhonatan Luiz Fiorio 5 , Jan-Ole Joswig 5 , Thomas Heine 5, 6, 7 , Larissa Schaper 8 , Christopher Bachetzky 9 , Rochus Schmid 8 , Roland A Fischer 3 , Andreas Pöppl 2 , Eike Brunner 9 , Stefan Kaskel 1
Affiliation
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Flexible Metal-Organic Frameworks respond to molecular or physical stimuli with spontaneous pore opening or closing, leading to applications in gas separation, storage, sensing, actuation etc. The review provides insights into decisive factors affecting switchability gained from combined simulations, in situ characterization methods and the dedicated design of pillared-layer MOF model materials varying in composition, structure, size, morphology, and disorder.
中文翻译：
了解 MOF 灵活性：以柱状层 MOF 作为模型系统的分析
柔性金属有机框架通过自发打开或关闭孔来响应分子或物理刺激，从而在气体分离、存储、传感、驱动等领域得到应用。该评论提供了对影响从组合模拟和原位表征方法中获得的可切换性的决定性因素的见解以及成分、结构、尺寸、形态和无序变化的柱层 MOF 模型材料的专门设计。
更新日期：2023-04-13
中文翻译：
了解 MOF 灵活性：以柱状层 MOF 作为模型系统的分析
柔性金属有机框架通过自发打开或关闭孔来响应分子或物理刺激，从而在气体分离、存储、传感、驱动等领域得到应用。该评论提供了对影响从组合模拟和原位表征方法中获得的可切换性的决定性因素的见解以及成分、结构、尺寸、形态和无序变化的柱层 MOF 模型材料的专门设计。
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