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Modulation of Uptake and Reactivity of Nitrogen Dioxide in Metal-Organic Framework Materials
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-04-07 , DOI: 10.1002/anie.202302602 Zi Wang 1, 2 , Alena M Sheveleva 1, 2 , Daniel Lee 3 , Yinlin Chen 1 , Dinu Iuga 4 , W Trent Franks 4 , Yujie Ma 1 , Jiangnan Li 1 , Lei Li 1 , Yongqiang Cheng 5 , Luke L Daemen 5 , Sarah J Days 6 , Anibal J Ramirez-Cuesta 5 , Bing Han 7 , Alexander S Eggeman 7 , Eric J L McInnes 1, 2 , Floriana Tuna 1, 2 , Sihai Yang 1 , Martin Schröder 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-04-07 , DOI: 10.1002/anie.202302602 Zi Wang 1, 2 , Alena M Sheveleva 1, 2 , Daniel Lee 3 , Yinlin Chen 1 , Dinu Iuga 4 , W Trent Franks 4 , Yujie Ma 1 , Jiangnan Li 1 , Lei Li 1 , Yongqiang Cheng 5 , Luke L Daemen 5 , Sarah J Days 6 , Anibal J Ramirez-Cuesta 5 , Bing Han 7 , Alexander S Eggeman 7 , Eric J L McInnes 1, 2 , Floriana Tuna 1, 2 , Sihai Yang 1 , Martin Schröder 1
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The reactivity of NO2 is modulated in a charged metal–organic framework, MFM-305-CH3, which leads to reaction between NO2 and framework Cl− to give nitrosyl chloride (NOCl) and NO3− anions. A higher NO2 dynamic uptake (6.58 mmol g−1) is achieved, compared with the analogous neutral material, MFM-305 (2.38 mmol g−1).
中文翻译：
金属有机骨架材料中二氧化氮的吸收和反应性的调节
NO 2的反应性在带电金属有机骨架MFM-305-CH 3中进行调节，导致NO 2与骨架Cl -发生反应，生成亚硝酰氯(NOCl) 和NO 3 -阴离子。与类似的中性材料MFM-305 (2.38 mmol g -1 ) 相比，实现了更高的NO 2动态吸收(6.58 mmol g -1 )。
更新日期：2023-04-07
中文翻译：
金属有机骨架材料中二氧化氮的吸收和反应性的调节
NO 2的反应性在带电金属有机骨架MFM-305-CH 3中进行调节，导致NO 2与骨架Cl -发生反应，生成亚硝酰氯(NOCl) 和NO 3 -阴离子。与类似的中性材料MFM-305 (2.38 mmol g -1 ) 相比，实现了更高的NO 2动态吸收(6.58 mmol g -1 )。
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