Ru Supported on p-phthalic acid-Mn Derived from a Mn Metal–Organic Framework for Thermo- and Electrocatalytic Synthesis of Ethylene-D4 Glycol,ChemSusChem

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Ru Supported on p-phthalic acid-Mn Derived from a Mn Metal–Organic Framework for Thermo- and Electrocatalytic Synthesis of Ethylene-D4 Glycol
ChemSusChem ( IF 7.5 ) Pub Date : 2023-04-03 , DOI: 10.1002/cssc.202202395
Fangjun Shao _{1,

2} , Fandong Ma ₁ , Yuanan Li ₁ , Wenjie Jiang ₁ , Zhongzhe Wei ₁ , Xing Zhong ₁ , Hong Wang ₂ , Ligeng Wang ₁ , Jianguo Wang ₁

Affiliation

Ethylene-D4 glycol has been prepared by Ru supported on MnBDC (MnBCD was an support of the catalyst,. derived from a Mn metal–organic framework prepared by Mn precursor and p-phthalic acid ) nanocatalyst both thermo- and electrocatalytic hydrogen isotope exchange (HIE) reaction. Hydrogen spillover and electron flow on the catalyst promote the high deuterated ratio of 97 % in thermo- and electrocatalytic systems, respectively.

中文翻译：

负载在源自锰金属有机框架的对苯二甲酸-锰上的 Ru 用于热催化和电催化合成乙二醇-D4

乙二醇-D4 是由负载在 MnBDC 上的 Ru 制备而成（MnBCD 是催化剂的载体，衍生自由 Mn 前体和对苯二甲酸制备的 Mn 金属有机骨架）纳米催化剂，具有热催化和电催化氢同位素交换功能（ HIE）反应。催化剂上的氢溢出和电子流分别促进热催化系统和电催化系统中 97% 的高氘化率。

更新日期：2023-04-03

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