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Primary cordierite with > 2.5 wt% CO2 from the UHT Bakhuis Granulite Belt, Surinam: CO2 fluid phase saturation during ultrahigh-temperature metamorphism
Contributions to Mineralogy and Petrology ( IF 3.5 ) Pub Date : 2023-04-03 , DOI: 10.1007/s00410-023-02003-1
Emond W. F. de Roever , Simon L. Harley , Jan M. Huizenga

The Paleoproterozoic Bakhuis Granulite Belt (BGB) in Surinam, South America, shows ultrahigh-temperature metamorphism (UHTM) at temperatures of around 1000 °C which, unusually, produced peak-to-near-peak cordierite with sillimanite and, in some cases, Al-rich orthopyroxene on a regional scale. Mg-rich cordierite (Mg/(Mg + Fe) = 0.88) in a sillimanite-bearing metapelitic granulite has a maximum birefringence of second-order blue (ca. 0.020) indicative of a considerable amount of CO2 (> 2 wt%) within its structural channels. SIMS microanalysis confirms the presence of 2.57 ± 0.19 wt% CO2, the highest CO2 concentration found in natural cordierite. This high CO2 content has enabled the stability of cordierite to extend into UHT conditions at high pressures and very low to negligible H2O activity. Based on a modified calibration of the H2O–CO2 incorporation model of Harley et al. (J Metamorph Geol 20:71–86, 2002), this cordierite occupies a stability field that extends from 8.8 ± 0.6 kbar at 750 °C to 11.3 ± 0.65 kbar at 1050 °C. Volatile-saturated cordierite with 2.57 wt% CO2 and negligible H2O (0.04 wt%) indicates fluid-present carbonic conditions with a CO2 activity near 1.0 at peak or near-peak pressures of 10.5–11.3 kbar under UHT temperatures of 950–1050 °C. The measured H2O content of the cordierite in the metapelite is far too low to be consistent with partial melting at 1000–1050 °C, implying either that nearly all of any H2O originally in this cordierite under UHT conditions was lost during post-peak cooling or that the cordierite was formed after migmatization. The high level of CO2 required to ensure fluid saturation of the c. 11 kbar UHT cordierite is proposed to have been derived from an external, possibly mantle, source.



中文翻译:

来自苏里南 UHT Bakhuis 麻粒岩带的含 > 2.5 wt% CO2 的原生堇青石:超高温变质过程中的 CO2 液相饱和

南美洲苏里南的古元古代 Bakhuis 麻粒岩带 (BGB) 在大约 1000 °C 的温度下显示出超高温变质作用 (UHTM),异常地产生峰到近峰堇青石和硅线石,在某些情况下,区域范围内富铝斜方辉石。含硅线石的变泥质麻粒岩中的富镁堇青石 (Mg/(Mg + Fe) = 0.88) 具有二级蓝色的最大双折射率 (ca. 0.020),表明含有大量 CO 2 (> 2 wt % )在其结构通道内。SIMS 微量分析证实存在 2.57 ± 0.19 wt% CO 2 ,​​这是天然堇青石中发现的最高 CO 2浓度。这种高 CO 2含量使堇青石的稳定性扩展到高压和非常低至可忽略的 H 2 O 活性的 UHT 条件。基于Harley 等人的H 2 O–CO 2结合模型的修正校准。(J Metamorph Geol 20:71–86, 2002),这种堇青石占据的稳定场从 750 °C 时的 8.8 ± 0.6 kbar 延伸到 1050 °C 时的 11.3 ± 0.65 kbar。含有 2.57 wt% CO 2和可忽略不计的 H 2 O (0.04 wt%) 的挥发性饱和堇青石表明在950 的 UHT 温度下,在 10.5–11.3 kbar 的峰值或近峰值压力下, CO 2活度接近 1.0 的流体存在的碳条件–1050°C。测得的H 2变泥质岩中堇青石的 O 含量太低,无法与 1000–1050 °C 的部分熔化相一致,这意味着在 UHT 条件下最初在这种堇青石中的几乎所有 H 2 O 在峰值后冷却过程中都消失了,或者堇青石是在混合化后形成的。确保 c 的流体饱和所需的高水平 CO 2 。11 kbar UHT 堇青石被认为来自外部来源,可能是地幔来源。

更新日期:2023-04-04
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