Paired Oxidative and Reductive Catalysis: Breaking the Potential Barrier of Electrochemical C(sp3)−H Alkenylation**,Angewandte Chemie International Edition

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Paired Oxidative and Reductive Catalysis: Breaking the Potential Barrier of Electrochemical C(sp3)−H Alkenylation**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-04-01 , DOI: 10.1002/anie.202301026
Long Zou ₁ , Xiaofan Wang ₁ , Siqi Xiang ₁ , Weipeng Zheng ₁ , Qingquan Lu ₁

Affiliation

A paired electrocatalysis strategy for alkane functionalization is reported for the first time, in which earth-abundant iron and nickel are employed as the anodic and cathodic catalysts, respectively. Importantly, C(sp³)−H alkenylation of alkanes with ultra-low oxidation potential (≈0.25 V vs. Ag/AgCl) is achieved using this protocol, providing a modular method for versatile mono- or multi-substituted olefins under mild conditions.

中文翻译：

配对氧化还原催化：打破电化学 C(sp3)−H 烯基化的势垒**

首次报道了一种用于烷烃功能化的配对电催化策略，其中地球丰富的铁和镍分别用作阳极和阴极催化剂。重要的是，使用该协议实现了具有超低氧化电位（≈0.25 V vs. Ag/AgCl）的烷烃的 C(sp 3 )−H 烯基化，为温和条件下的多功能单取代或多取代烯烃提供了模块化^方法.

更新日期：2023-04-01

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