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Effect of CeO2 redox properties on the catalytic activity of Pt-CeOx over irreducible SiO2 support for methylcyclohexane (MCH) dehydrogenation
Applied Surface Science ( IF 6.3 ) Pub Date : 2023-03-31 , DOI: 10.1016/j.apsusc.2023.157134
Munjeong Jang , Subin Choi , Yoondo Kim , Junyoung Cha , Ah-Reum Kim , Hyangsoo Jeong , Yongmin Kim , Sun Hee Choi , Suk Woo Nam , Jongwoo Lim , Chang Won Yoon , Hyuntae Sohn

A highly reducible CeO2 surface was prepared on a SiO2 support to investigate the effect of redox properties of CeO2 on the catalytic activity of Pt/CeO2-SiO2 for MCH dehydrogenation. Characterization of the Pt/CeO2-SiO2 catalyst revealed a significantly higher Pt dispersion than Pt/micro-sized CeO2 and Pt/SiO2. The well-dispersed Pt particles averaging 1.1 nm in size (Pt/CeO2-SiO2) were primarily attributed to the high surface concentration of oxygen vacancies, which provided abundant defect sites that stabilized the Pt particles from sintering. Hydrogen released from MCH dehydrogenation was approximately 5–6 times greater with high selectivity towards toluene products for Pt/CeO2-SiO2 compared to its counterparts. The excellent catalytic activity of Pt/CeO2-SiO2 was attributed to the presence of rich oxygen vacancies on the CeO2 surface, which was significantly reduced under MCH dehydrogenation conditions, resulting in faster toluene desorption.



中文翻译:

CeO2 氧化还原特性对 Pt-CeOx 在不可还原 SiO2 载体上甲基环己烷 (MCH) 脱氢催化活性的影响

在SiO 2载体上制备高度可还原的CeO 2表面以研究CeO 2的氧化还原性质对Pt/CeO 2 -SiO 2催化MCH脱氢活性的影响。Pt/CeO 2 -SiO 2催化剂的表征表明,Pt 分散度明显高于 Pt/微型 CeO 2和 Pt/SiO 2。分散良好的 Pt 颗粒平均尺寸为 1.1 nm (Pt/CeO 2 -SiO 2)主要归因于氧空位的高表面浓度,它提供了丰富的缺陷位点,稳定了 Pt 颗粒的烧结。与对应物相比,MCH 脱氢释放的氢气大约高 5-6 倍,对 Pt/CeO 2 -SiO 2的甲苯产品具有高选择性。Pt/CeO 2 -SiO 2优异的催化活性归因于CeO 2表面存在丰富的氧空位,在MCH脱氢条件下氧空位显着减少,导致甲苯脱附更快。

更新日期:2023-03-31
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