氧化钒：相图、结构、合成和应用,Chemical Reviews

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氧化钒：相图、结构、合成和应用
Chemical Reviews ( IF 51.4 ) Pub Date : 2023-03-27 , DOI: 10.1021/acs.chemrev.2c00546
Peng Hu _{1,

2} , Ping Hu _{3,

4} , Tuan Duc Vu ₂ , Ming Li ₅ , Shancheng Wang ₂ , Yujie Ke _{2,

6} , Xianting Zeng ₇ , Liqiang Mai _{3,

4} , Yi Long _{2,

8}

Affiliation

School of Physics, Northwest University, Xi'an 710069, P. R. China.
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei, China.
Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan 528200, Guangdong, China.
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Science, Hefei 230031, P. R. China.
Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Innovis #08-03, Singapore 138634, Republic of Singapore.
Singapore Institute of Manufacturing Technology (SIMTech), 2 Fusionopolis Way, #08-04 Innovis, Singapore 138634, Singapore.
Department of Electronic Engineering, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, SAR 999077, China.

具有多氧化态和各种晶体结构的钒氧化物具有独特的电学、光学、光电和磁学性质，可用于各种应用。在过去的 30 年里，人们在研究基础科学和探索钒氧化物材料在离子电池、水分解、智能窗户、超级电容器、传感器等方面的潜力方面做出了重大努力。本综述重点介绍了一些热力学稳定和亚稳态钒氧化物的合成方法和应用的最新进展，包括但不限于V 2 _O 3 _、 V ₃ O ₅、VO ₂、V ₃ O ₇、V ₂O ₅、V ₂ O ₂、V ₆ O ₁₃和V ₄ O ₉。我们从有关 V-O 系统相图的教程开始。第二部分详细介绍了每种钒氧化物的晶体结构、合成方案和应用，尤其是在电池、催化剂、智能窗和超级电容器中的应用。最后，我们简要介绍了材料和设备改进如何解决当前的缺陷。这篇综合综述可以加速相关应用中新型钒氧化物结构的开发。

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更新日期：2023-03-27

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