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Precise synthesis of schwarzite carbon: hypothesis or reality?
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2023-03-27 , DOI: 10.1039/d3qo00202k Ming-Wei Wang 1 , Zuoyu Li 1 , Yujian Liu 1 , Wei Jiang 1 , Zhaohui Wang 1
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2023-03-27 , DOI: 10.1039/d3qo00202k Ming-Wei Wang 1 , Zuoyu Li 1 , Yujian Liu 1 , Wei Jiang 1 , Zhaohui Wang 1
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The creation of new carbon allotropes has provided tremendous opportunities in the fields of chemistry, physics, and materials science. As a new member of carbon allotropes, schwarzite carbon has been predicted to present unique physical and chemical properties. However, such a beautiful structure with broad prospects remains hypothetical. The bottom-up organic synthesis has emerged as a feasible way to synthesize the negatively curved fragments, which can serve as key building blocks to synthesize schwarzite carbon precisely. In this study, we summarize the research progress aimed at combining several means to achieve the precise synthesis of schwarzite carbon. In particular, by selecting Schwarzite P192 as an example, we designed the key units and presented a theoretical prediction.
中文翻译：
黑石英碳的精确合成：假设还是现实？
新碳同素异形体的产生为化学、物理和材料科学领域提供了巨大的机遇。作为碳同素异形体的新成员，蓝石英碳被预测具有独特的物理和化学性质。然而，这样一个具有广阔前景的美丽结构仍然是假设。自下而上的有机合成已成为合成负弯曲碎片的可行方法，它可以作为精确合成黑石英碳的关键构件。在这项研究中，我们总结了旨在结合多种方法实现黑石英碳的精确合成的研究进展。特别地，我们以 Schwarzite P192 为例，设计了关键单元并给出了理论预测。
更新日期：2023-03-27
中文翻译：
黑石英碳的精确合成：假设还是现实？
新碳同素异形体的产生为化学、物理和材料科学领域提供了巨大的机遇。作为碳同素异形体的新成员，蓝石英碳被预测具有独特的物理和化学性质。然而，这样一个具有广阔前景的美丽结构仍然是假设。自下而上的有机合成已成为合成负弯曲碎片的可行方法，它可以作为精确合成黑石英碳的关键构件。在这项研究中，我们总结了旨在结合多种方法实现黑石英碳的精确合成的研究进展。特别地，我们以 Schwarzite P192 为例，设计了关键单元并给出了理论预测。
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