Materialia Pub Date : 2023-03-22 , DOI: 10.1016/j.mtla.2023.101755 Wentao Jia , Xin Song , Yao Liu , Tianyu Ma
The 2:17-type Sm-Co-Fe-Cu-Zr high-temperature magnets exhibit unique cellular nanostructure, with Zr-rich lamellar phase (Z-phase) penetrating through the 2:17R nanocells and 1:5H cell boundaries. In this work, a face-centered cubic (FCC) Zr-rich lamellar phase was identified in an Fe-rich Sm25Co42.9Fe23.5Cu5.6Zr3.0 (wt.%) magnet. The orientation relationship between FCC and 2:17R phases is [100]-2:17 ∥ [10]-FCC and (001)-2:17R ∥ (111)-FCC. Unlike the previously-reported hexagonal or rhombohedral Z-phases that are fully coherent with 2:17R or 1:5H phases, both the broad interphase (111)-FCC/(001)-2:17R and the (22)-FCC/(010)-2:17R interphase at the peripheries of the FCC Z-phase exhibit semi-coherent morphology, due to the large lattice mismatch. The semi-coherent FCC Z-phase can be attributed to the thickening of the coherent Z-phase that gradually loses coherency, as a result of a gradual reduction in elastic strain energy and interfacial energy. This finding may add new insights into the solid-state phase transitions of Sm-Co-based magnets.
中文翻译:
2:17 型高 Fe 含量 Sm-Co-Fe-Cu-Zr 磁体中半共格富 Zr 层状相的形成
2:17 型 Sm-Co-Fe-Cu-Zr 高温磁体具有独特的细胞纳米结构,富 Zr 层状相(Z 相)穿透 2:17R 纳米细胞和 1:5H 细胞边界。在这项工作中,在富含 Fe 的 Sm 25 Co 42.9 Fe 23.5 Cu 5.6 Zr 3.0 (wt.%) 磁体中鉴定出面心立方 (FCC) 富 Zr 层状相。FCC与2:17R相的取向关系为[100]-2:17∥[10]-FCC 和 (001)-2:17R ∥ (111)-FCC。与先前报道的与 2:17R 或 1:5H 相完全相干的六方或菱形 Z 相不同,宽界面 (111)-FCC/(001)-2:17R 和 (22)-FCC/(010)-2:17R 界面在 FCC Z 相的外围表现出半相干形态,这是由于大的晶格失配。半相干 FCC Z 相可归因于相干 Z 相增厚,逐渐失去相干性,这是弹性应变能和界面能逐渐降低的结果。这一发现可能会为 Sm-Co 基磁体的固态相变增加新的见解。