Russian Journal of Inorganic Chemistry ( IF 1.8 ) Pub Date : 2023-03-21 , DOI: 10.1134/s0036023622602112
S. A. Tuychiev , A. A. Sidikov , A. S. Togasharov , B. S. Zakirov
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Abstract
The NaClO3⋅CO(NH2)2–CS(NH2)2–H2O system has been studied using binary systems and eight internal cuts and a polythermal solubility diagram has been constructed in the temperature range from –34.2 to 48.2°C. The phase diagram of the polythermal solubility of the system has delimitated the crystallization fields of ice, CO(NH2)2, NaClO3⋅CO(NH2)2, and CS(NH2)2. This system belongs to a simple eutonic type, the components have retained their individuality and have shown good solubility in water. In the [60%NaClO3⋅CO(NH2)2 + 40%H2O]–[CS(NH2)2] section, changes in crystallization temperature, viscosity, density, pH, and refraction indices of solutions in various component ratios have been studied and a “composition-properties” diagram has been constructed.
中文翻译:

NaClO3·CO(NH2)2–CS(NH2)2–H2O 体系中组分的溶解度
摘要
NaClO 3 ⋅CO(NH 2 ) 2 –CS(NH 2 ) 2 –H 2 O 系统已使用二元系统和八个内部切割进行了研究,并在 –34.2 至 48.2° 的温度范围内构建了多热溶解度图C。系统的多热溶解度相图划定了冰、CO(NH 2 ) 2、NaClO 3 ⋅ CO(NH 2 ) 2和CS(NH 2 ) 2的结晶场. 该体系属于简单的共渗型,组分保留了各自的个性,在水中表现出良好的溶解性。在[60%NaClO 3 ⋅CO(NH 2 ) 2 + 40%H 2 O]–[CS(NH 2 ) 2 ]部分,不同溶液的结晶温度、粘度、密度、pH值和折射率的变化研究了成分比率并构建了“组成-特性”图。