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Influence of SrCO3‐doping on the microstructure and electrical properties of ZnO–(Bi2O3/Sb2O3) varistor ceramics
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2023-03-20 , DOI: 10.1007/s10854-023-10092-8
Faiçal Kharchouche , Abdelkrim Zebar

The objective desired is the elaboration of varistors based on zinc oxide-doped by the addition of SrCO3 with a different quantity of 1, 2, 3 and 4 mol% SrCO3, such that the base quantity is 0.5 mol% of Bi2O3, 0.5 mol% of Sb2O3 and 99 mol% of ZnO. The varistors were sintered at the temperature 1000–1200 °C in a solid way, the microstructural characteristics are carried out by X-ray diffraction (XRD) and scanning electron microscopy (SEM) where we could determine several secondary phases such as Zn2.33Sb0.67O4, Bi3Sb3Zn2O14, Bi6Sr2O11, Bi2O3 and Sb2O3 have been formed. These latter were the result of a competition between diffusion and segregation of oxides into the grain core and the grain boundaries of matrix. High SrCO3 content was originally the segregation of the Bi2O3, Sb2O3 oxides and of solid solution (Bi6Sr2O11) in the grain boundaries. Grain size, relative density, electrical permittivity (\({\upvarepsilon }^{\mathrm{^{\prime}}}\)), loss factor (tanδ) and leakage current (IL) are reduced when increasing the amount of SrCO3, on the other hand, the non-linearity coefficient (α) and electric voltage (Vb) increased, the sample with the highest amount of SrCO3 presents a better coefficient of non-linearity 29.37 and 1020 V in comparison with others varistors. In all of these results it can be said that the addition of SrCO3 was given an improvement on the electrical property, dielectric and microstructure of the base varistor. The obtained varistor would be very promising in low-voltage power transmission systems.



中文翻译:

SrCO3掺杂对ZnO-(Bi2O3/Sb2O3)压敏陶瓷微观结构和电性能的影响

期望的目标是通过添加具有不同量的 1、2、3 和 4 mol% SrCO 3的 SrCO 3来制备基于氧化锌掺杂的变阻器,使得基本量为 0.5 mol% Bi 2 O 3、0.5mol%的Sb 2 O 3和99mol%的ZnO。压敏电阻在 1000–1200 °C 的温度下以固体方式烧结,微观结构特征通过 X 射线衍射 (XRD) 和扫描电子显微镜 (SEM) 进行,我们可以确定几个第二相,如 Zn 2.33 Sb 0.67 O 4 , Bi 3 Sb 3 Zn 2 O如图14所示,形成了Bi 6 Sr 2 O 11、Bi 2 O 3、Sb 2 O 3 。后者是氧化物扩散和偏析到晶核和基体晶界之间竞争的结果。高SrCO 3含量最初是Bi 2 O 3、Sb 2 O 3氧化物和固溶体(Bi 6 Sr 2 O 11 )在晶界中的偏析。晶粒尺寸、相对密度、介电常数 ( \({\upvarepsilon }^{\mathrm{^{\prime}}}\))、损耗因数(tan δ )和漏电流( I L )随着SrCO 3含量的增加而降低,另一方面,非线性系数( α )和电压( V b )增加,样品与与其他变阻器相比,SrCO 3的最高含量呈现出更好的非线性系数 29.37 和 1020 V。在所有这些结果中,可以说添加 SrCO 3改善了基础变阻器的电性能、介电和微观结构。获得的变阻器在低压电力传输系统中非常有前途。

更新日期:2023-03-21
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