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High energy storage performance in AgNbO3 relaxor ferroelectric films induced by nanopillar structure
Journal of Materials Science & Technology ( IF 11.2 ) Pub Date : 2023-03-11 , DOI: 10.1016/j.jmst.2023.03.004
Xiang Li , Jing Wang , Xingyuan San , Ning Wang , Lei Zhao

Inspired by the increasing demand for energy-storage capacitors in electrical and electronic systems, dielectrics with high energy-storage performance have attracted more and more attention. AgNbO3-based lead-free ceramics serve as one of the most promising environmental-friendly candidates. However, their energy storage optimization is seriously limited by the low breakdown strength. Fortunately, thin film as a form of AgNbO3 materials can effectively improve the breakdown strength. In this work, AgNbO3 film with ∼550 nm in thickness was deposited on SrRuO3/(001)SrTiO3 using pulsed laser deposition. The AgNbO3 film reveals typical relaxor ferroelectric hysteresis loops due to the new nanopillar structure, which contributes to high breakdown strength of up to 1200 kV cm–1. Benefiting from the high breakdown strength, a recoverable energy storage density of 10.3 J cm–3 and an energy efficiency of 72.2% are obtained in the AgNbO3 film, which demonstrates the promising prospect of AgNbO3 film for energy storage applications.



中文翻译:

纳米柱结构诱导 AgNbO3 弛豫铁电薄膜的高储能性能

受电气和电子系统对储能电容器日益增长的需求的启发,具有高储能性能的电介质受到越来越多的关注。AgNbO 3基无铅陶瓷是最有前途的环保候选材料之一。然而,它们的储能优化受到低击穿强度的严重限制。幸运的是,AgNbO 3薄膜材料可以有效提高击穿强度。在这项工作中,使用脉冲激光沉积将厚度约为 550 nm 的 AgNbO 3薄膜沉积在 SrRuO 3 /(001)SrTiO 3上。AgNbO 3由于新的纳米柱结构,薄膜揭示了典型的弛豫铁电磁滞回线,这有助于高达 1200 kV cm –1的高击穿强度。得益于高击穿强度,AgNbO 3薄膜的可恢复储能密度为10.3 J cm –3 ,能量效率为72.2%,展示了AgNbO 3薄膜在储能应用方面的广阔前景。

更新日期:2023-03-11
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