Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2023-03-11 , DOI: 10.1016/j.snb.2023.133633 Jiangnan Chang , Cong Qin , Weijie Guo , Linghao Zhu , Yan Zhang , Yan Wang , Jianliang Cao
High-performance NO2 gas sensor at room temperature is vital in daily life. Herein, the performance of SnS2 hierarchical structure modified by Au nanoparticles was explored as a NO2 sensing material at room temperature. The samples were synthesized by solvothermal method and subsequent in-situ reduction method which could be confirmed by the analysis results of X-ray powder diffractometer (XRD), field-emission scanning electronic microscope (FESEM), transmission electron microscopy (TEM) and X-ray photoelectron spectra (XPS). Through a series of gas sensing measurements, the sensor based on Au-SnS2 possesses outstanding NO2 sensing properties under visible light at room temperature, including high response at trace concentration (14.24/5 ppm), excellent response/recovery time (29/148 s), low detection limit (36 ppb), satisfactory selectivity and repeatability. Combined with the first-principles calculations, the enhanced sensing performance can be contributed to the modification of Au with rich charge transfer (−0.5153 e) and the local surface plasmon resonance (LSPR) between Au and visible light with the enhanced optical absorption capacity and carrier density of the material. This work proffers opportunities for real-time NO2 detection in daily life.
中文翻译:
可见光增强 Au 纳米粒子改性 SnS2 室温下 NO2 传感性能
室温下的高性能 NO 2气体传感器在日常生活中至关重要。在此,探讨了由Au 纳米粒子修饰的SnS 2分级结构在室温下作为NO 2传感材料的性能。样品通过溶剂热法和随后的原位还原法合成,可以通过X射线粉末衍射仪(XRD),场发射扫描电子显微镜(FESEM),透射电子显微镜(TEM)和X的分析结果来证实。 -射线光电子能谱 (XPS)。通过一系列气敏测量,基于 Au-SnS 2 的传感器具有出色的 NO 2室温下可见光下的传感特性,包括痕量浓度 (14.24/5 ppm) 的高响应、出色的响应/恢复时间 (29/148 s)、低检测限 (36 ppb)、令人满意的选择性和可重复性。结合第一性原理计算,增强的传感性能有助于 Au 的修饰,具有丰富的电荷转移(-0.5153 e)和 Au 与可见光之间的局域表面等离子体共振(LSPR),具有增强的光吸收能力和材料的载流子密度。这项工作为日常生活中的实时 NO 2检测提供了机会。