Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis,Journal of the American Chemical Society

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Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2011-11-23 , DOI: 10.1021/ja208068w
Dipannita Kalyani ₁ , Kate B McMurtrey , Sharon R Neufeldt , Melanie S Sanford

Affiliation

This communication describes the development of a room-temperature ligand-directed C-H arylation reaction using aryldiazonium salts. This was achieved by the successful merger of palladium-catalyzed C-H functionalization and visible-light photoredox catalysis. The new method is general for a variety of directing groups and tolerates many common functional groups.

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