Bi₂O₂CO₃/Bi₂S₃ heterojunction was prepared by one-step hydrothermal method, where Bi(NO₃)₃ was employed as Bi source, Na₂S was used as a sulfur source, and CO(NH₂)₂ was adopted as C source. The load of Bi₂S₃ was adjusted by changing the content of Na₂S. The prepared Bi₂O₂CO₃/Bi₂S₃ illustrated strong photocatalytic activity towards dibutyl phthalate (DBP) degradation. The degradation rate was 73.6% under the irradiation of visible light for 3 h, which were 3.5 and 1.87 times for Bi₂O₂CO₃ and Bi₂S₃, respectively. In addition, the mechanism for the enhanced photoactivity was investigated. After combined with Bi₂S₃, the formed heterojunction structure inhibited the recombination of photogenerated electron-hole pair, improved the visible light adsorption, and accelerated the migration rate of the photogenerated electron. As a result, analysis of the radical formation and the energy band structure revealed that Bi₂O₂CO₃/Bi₂S₃ was consistent with the S-scheme heterojunction model. The S-scheme heterojunction allowed the Bi₂O₂CO₃/Bi₂S₃ to possess high photocatalytic activity. The prepared photocatalyst presented acceptable cycle application stability. This work not only develops a facile one-step synthesis technique for Bi₂O₂CO₃/Bi₂S₃, and also provides a good platform for the degradation of DBP.