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Pyrene-Based Covalent Organic Frameworks for Photocatalytic Hydrogen Peroxide Production
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-03-10 , DOI: 10.1002/anie.202216719 Jiamin Sun 1 , Himanshu Sekhar Jena 1 , Chidharth Krishnaraj 1 , Kuber Singh Rawat 2 , Sara Abednatanzi 1 , Jeet Chakraborty 1 , Andreas Laemont 1 , Wanlu Liu 1 , Hui Chen 1 , Ying-Ya Liu 3 , Karen Leus 1 , Henk Vrielinck 4 , Veronique Van Speybroeck 2 , Pascal Van Der Voort 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-03-10 , DOI: 10.1002/anie.202216719 Jiamin Sun 1 , Himanshu Sekhar Jena 1 , Chidharth Krishnaraj 1 , Kuber Singh Rawat 2 , Sara Abednatanzi 1 , Jeet Chakraborty 1 , Andreas Laemont 1 , Wanlu Liu 1 , Hui Chen 1 , Ying-Ya Liu 3 , Karen Leus 1 , Henk Vrielinck 4 , Veronique Van Speybroeck 2 , Pascal Van Der Voort 1
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Four highly porous pyrene-based covalent organic frameworks (COFs) were prepared for photocatalytic H2O2 generation. The reported findings highlight that the presence of pyrene active sites in very close proximity leads to unwanted H2O2 decomposition. Accordingly, a biphasic system (benzyl alcohol and water) was employed to inhibit H2O2 decomposition.
中文翻译：
用于光催化过氧化氢生产的基于芘的共价有机骨架
制备了四种高度多孔的基于芘的共价有机框架 (COF) 用于光催化 H 2 O 2生成。报告的研究结果强调，非常接近的芘活性位点的存在会导致不需要的 H 2 O 2分解。因此，采用双相系统（苯甲醇和水）来抑制H 2 O 2分解。
更新日期：2023-03-10
中文翻译：
用于光催化过氧化氢生产的基于芘的共价有机骨架
制备了四种高度多孔的基于芘的共价有机框架 (COF) 用于光催化 H 2 O 2生成。报告的研究结果强调，非常接近的芘活性位点的存在会导致不需要的 H 2 O 2分解。因此，采用双相系统（苯甲醇和水）来抑制H 2 O 2分解。
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