Two Unprecedented Reactions of Nitrosyl Triflate: NO+-Induced Cationic Cascade Cyclization and C═C Oxidative Cleavage,Organic Letters

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Two Unprecedented Reactions of Nitrosyl Triflate: NO+-Induced Cationic Cascade Cyclization and C═C Oxidative Cleavage
Organic Letters ( IF 4.9 ) Pub Date : 2023-03-10 , DOI: 10.1021/acs.orglett.3c00353
G Sudhakar Reddy ₁ , E J Corey ₁

Affiliation

Nitrosyl triflate is shown to react with olefins in a CH₂Cl₂ solution by three different pathways depending on structure and reaction conditions: (1) cationic cyclization, (2) C═C cleavage, and (3) allylic nitrosation. Possible reaction pathways are described.

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