Food Chemistry ( IF 8.5 ) Pub Date : 2023-03-08 , DOI: 10.1016/j.foodchem.2023.135920 Jingjing Chen 1 , Peipei Li 1 , Yixiu Han 1 , Yuchen Li 1 , Yingxiang Du 1
Highly photoluminescent N-doped carbon quantum dots (N-CDs) which the quantum yield reached 63% were prepared through hydrothermal treatment. The obtained N-CDs displayed a uniform distribution of particle size, superior stability in high-salt conditions, and excellent sensitivity. A green fluorescence probe based on N-CDs was constructed for ultrasensitive determination of myricetin in vine tea on account of the static quenching. The N-CDs presented excellent linear fluorescence response in the concentration range of 0.2–40 μM and 56–112 μM and with a low detection limit of 56 nM. Additionally, the practicability of the probe was verified in spiked vine tea sample, and the satisfactory recoveries of myricetin varied from 98.8% to 101.2%, with relative standard deviations in the range of 1.52%-3.48%. It is the first time to employ N-CDs without any material modification as a fluorescence sensor to detect myricetin, which is a promising approach to expand the path for myricetin screening.
中文翻译:
高光致发光氮掺杂碳量子点作为测定杨梅素的绿色荧光探针
通过水热处理制备了量子产率达到63%的高光致发光N掺杂碳量子点(N -CDs)。获得的N -CDs 显示出均匀的粒径分布,在高盐条件下具有优异的稳定性和出色的灵敏度。基于静态猝灭构建了一种基于N -CDs 的绿色荧光探针,用于超灵敏测定藤茶中的杨梅素。N号-CD 在 0.2–40 μM 和 56–112 μM 的浓度范围内表现出出色的线性荧光响应,检测限低至 56 nM。此外,在加标藤茶样品中验证了该探针的实用性,杨梅素的回收率在98.8%至101.2%之间,相对标准偏差在1.52%-3.48%之间。这是首次使用未经任何材料修饰的N -CDs作为荧光传感器检测杨梅素,有望拓展杨梅素筛选途径。