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A porous Li4SiO4 ceramic separator for lithium-ion batteries
Ionics ( IF 2.4 ) Pub Date : 2023-03-07 , DOI: 10.1007/s11581-023-04940-0
Kuo Yang , Zehai Zhang , Ke Xu , Ye Li , Fangfei Li , Bing Xue , Xiaopeng Gu

Using diatomite and lithium carbonate as raw materials, a porous Li4SiO4 ceramic separator is prepared by sintering. The separator has an abundant and uniform three-dimensional pore structure, excellent electrolyte wettability, and thermal stability. Lithium ions are migrated through the electrolyte and uniformly distributed in the three-dimensional pores of the separator. The sintering temperature has an important influence on the composition of the ceramic separator. When the sintering temperature reaches 650 °C, pure Li4SiO4 is synthesized. The large porosity and excellent electrolyte affinity provide a maximum ionic conductivity of 1.18 mS cm-1 for the LSCS650 ceramic separator. After 120 charge-discharge cycles, the lithium iron phosphate battery assembled with the LSCS650 separator has a discharge specific capacity of 128.4 mA h g-1 and a capacity retention rate of nearly 100% at a current density of 1 C. Meanwhile, at a high current density of 10 C, the cell still has a discharge capacity of 71.4 mA h g-1. Therefore, the Li4SiO4 ceramic separator has a good application prospect in high-power lithium-ion batteries.



中文翻译:

用于锂离子电池的多孔 Li4SiO4 陶瓷隔膜

以硅藻土和碳酸锂为原料,采用烧结法制备多孔Li 4 SiO 4陶瓷隔膜。该隔膜具有丰富均匀的三维孔结构、优异的电解液润湿性和热稳定性。锂离子通过电解质迁移并均匀分布在隔膜的三维孔隙中。烧结温度对陶瓷隔板的成分有重要影响。当烧结温度达到650℃时,合成了纯Li 4 SiO 4 。大孔隙率和出色的电解质亲和力提供了 1.18 mS cm -1的最大离子电导率适用于 LSCS650 陶瓷分离器。采用LSCS650隔膜组装的磷酸铁锂电池经过120次充放电循环后,放电比容量为128.4 mA hg -1,在1 C电流密度下容量保持率接近100%。同时,在高倍率下在 10 C 的电流密度下,电池仍具有 71.4 mA hg -1的放电容量。因此,Li 4 SiO 4陶瓷隔膜在大功率锂离子电池中具有良好的应用前景。

更新日期:2023-03-07
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