Z-scheme Ag₃PO₄ @MoS₂ photocatalyst was constructed by decorating MoS₂ nanosheets on Ag₃PO₄ cubes for recovering hydrogen energy from antibiotic wastewater. Abundant oxygen vacancies (Vo) distributed along with Ag₃PO₄ cube surface are responsible for MoS₂ lattice distortion by enabling 2 H phase MoS₂ around Vo partially transform in 1 T phase. Free radicals trapping and theoretical calculation approve that Vo act as intermediate medium of charge transferring in Z-scheme Ag₃PO₄ @MoS₂ system. On the strength of Vo and mixed phase of MoS₂ providing more exposed active sites, superior conductivity and excellent stability, photocatalytic hydrogen recovery over Ag₃PO₄ @MoS₂ is high up to 54.01 µmol·g⁻¹·h⁻¹ from norfloxacin wastewater (degradation efficiency: 88.36%). It is found that bandgap matching between antibiotics molecule and Ag₃PO₄ @MoS₂ accounts for hydrogen recovery kinetics. H protons could be donated in the process of decyclopropylaton, dihydroxylation and demethylation for antibiotic degradation. This work presents new lines for seeking greater sustainability by managing antibiotics wastewater resource.

Z型Ag ₃ PO ₄ @MoS ₂光催化剂是通过在Ag ₃ PO _{4立方体上装饰MoS 2}纳米片构建的，用于从抗生素废水中回收氢能。沿Ag ₃ PO ₄立方体表面分布的大量氧空位(Vo)通过使Vo周围的2 H相MoS ₂部分转变为1 T相而导致MoS _{2晶格畸变。自由基捕获和理论计算证实Vo在Z型Ag 3} PO ₄ @MoS ₂中作为电荷转移的中间介质系统。凭借 Vo 的强度和 MoS ₂的混合相提供更多暴露的活性位点、优异的导电性和出色的稳定性，Ag ₃ PO ₄ @MoS ₂上的光催化氢回收率高达 54.01 µmol·g ^-1 ·h ^-1来自诺氟沙星废水（降解效率：88.36%）。发现抗生素分子与Ag ₃ PO ₄ @MoS _{2之间的带隙匹配}考虑氢回收动力学。H 质子可以在脱环丙基化、二羟基化和去甲基化过程中提供给抗生素降解。这项工作提出了通过管理抗生素废水资源寻求更大可持续性的新思路。