Heterobimetallic NiFe Cooperative Molecular Water Oxidation Catalyst,Angewandte Chemie International Edition

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Heterobimetallic NiFe Cooperative Molecular Water Oxidation Catalyst
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-03-04 , DOI: 10.1002/anie.202218859
Hong-Tao Zhang ₁ , Yu-Hua Guo ₁ , Yao Xiao ₁ , Hao-Yi Du _{1,

2} , Ming-Tian Zhang ₁

Affiliation

A family of structurally well-defined bimetallic complexes (FeFe, NiFe, NiNi, ZnFe, NiZn) was used as a molecular platform to understand Ni/Fe cooperative water oxidation mechanism. The results disclosed that O−O bond formed via intramolecular oxyl-oxo coupling between bridged O radical and terminal Fe^IV=O moiety in Ni^III(μ-O)Fe^IV=O species, which provides a helpful guidance for rational design of heterobimetallic catalysts.

中文翻译：

异质双金属NiFe协同分子水氧化催化剂

一系列结构明确的双金属配合物（FeFe、NiFe、NiNi、ZnFe、NiZn）被用作分子平台来理解 Ni/Fe 协同水氧化机制。结果表明，Ni ^III ( μ -O)Fe ^IV =O 物种中桥接 O 自由基与末端 Fe ^IV =O 部分之间通过分子内氧-氧偶联形成 O−O 键，这为异质双金属的合理设计提供了有益的指导。催化剂。

更新日期：2023-03-04

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