Electroreduction Enables Regioselective 1,2-Diarylation of Alkenes with Two Electrophiles,Angewandte Chemie International Edition

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Electroreduction Enables Regioselective 1,2-Diarylation of Alkenes with Two Electrophiles
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-02-24 , DOI: 10.1002/anie.202219166
Weijie Yu ₁ , Shengchun Wang ₂ , Meng He ₂ , Zhou Jiang ₁ , Yi Yu ₂ , Jinping Lan ₁ , Jin Luo ₁ , Pengjie Wang ₂ , Xiaotian Qi ₂ , Tao Wang ₁ , Aiwen Lei _{1,

2}

Affiliation

Utilizing cyanoarene radical anions as redox-mediators, the electrochemical regioselective 1,2-diarylation of alkenes with cyanoarenes and aryl halides takes place in the absence of transition-metal catalysts. The merit of this method has been well demonstrated by its wide scope, excellent regioselectivity, and powerful scale-up synthesis.

中文翻译：

电还原使具有两个亲电子试剂的烯烃区域选择性 1,2-二芳基化成为可能

利用氰基芳烃自由基阴离子作为氧化还原介体，烯烃与氰基芳烃和芳基卤化物的电化学区域选择性 1,2-二芳基化反应在没有过渡金属催化剂的情况下发生。该方法的优点已通过其广泛的范围、出色的区域选择性和强大的放大合成得到了很好的证明。

更新日期：2023-02-24

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