Direct synthesis of phosphorotrithioates from [TBA][P(SiCl3)2] and disulfides,Organic & Biomolecular Chemistry

当前位置： X-MOL 学术 › Org. Biomol. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Direct synthesis of phosphorotrithioates from [TBA][P(SiCl3)2] and disulfides
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2023-02-21 , DOI: 10.1039/d2ob02285k
Hui Luo ₁ , Ming Li ₁ , Xi-Cun Wang ₁ , Zheng-Jun Quan ₁

Affiliation

Sulfur-containing organophosphorus molecules have played a pivotal role in organic synthesis, pharmaceutical pesticides and functional materials, thereby motivating researchers worldwide to establish S–P bonds from more environmentally friendly phosphorus sources. In this study, a novel method was developed for constructing S–P bonds, specifically by reacting the inorganic phosphorus derivative TBA[P(SiCl₃)₂] with sulfur-containing compounds under mild conditions. This method demonstrates the advantages of low energy consumption, mild reaction conditions and environmental friendliness. Moreover, this protocol—as a green synthesis method to replace the use of white phosphorus in the production of organophosphorus compounds (OPCs)—achieved the functional conversion of “inorganic phosphorus to organic phosphorus”, in line with the national green development strategy.

中文翻译：

[TBA][P(SiCl3)2]和二硫化物直接合成三硫代磷酸酯

含硫有机磷分子在有机合成、医药农药和功能材料中发挥了举足轻重的作用，从而促使全世界的研究人员从更环保的磷源中建立 S-P 键。在这项研究中，开发了一种构建 S-P 键的新方法，特别是通过与无机磷衍生物 TBA[P(SiCl ₃ ) _2反应] 在温和条件下与含硫化合物。该方法具有能耗低、反应条件温和、环境友好等优点。此外，该方案作为替代白磷生产有机磷化合物（OPCs）的绿色合成方法，实现了“无机磷向有机磷”的功能转化，符合国家绿色发展战略。

更新日期：2023-02-21

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南