Photo-responsive Single-Molecule Magnet Showing 0D to 1D Single-Crystal-to-Single-Crystal Structural Transition and Hysteresis Modulation,Angewandte Chemie International Edition

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Photo-responsive Single-Molecule Magnet Showing 0D to 1D Single-Crystal-to-Single-Crystal Structural Transition and Hysteresis Modulation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-02-20 , DOI: 10.1002/anie.202300088
Xin-Da Huang _{1,

2} , Xiu-Fang Ma ₁ , Li-Min Zheng ₁

Affiliation

A reversible photo-induced single-crystal-to-single-crystal structural transformation was achieved for a mononuclear dysprosium-anthracene compound to form a 1D coordination polymer. This compound displays photoswitchable SMM properties with reduced effective spin-reversal energy barrier, narrowed butterfly-like hysteresis loop, and decreased blocking temperature.

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