Inorganic Chemistry Communications ( IF 4.4 ) Pub Date : 2023-02-01 , DOI: 10.1016/j.inoche.2023.110458 Jian Huang , Lin Hu , Zhong Yang , Jianping Li , Ping Wang , Yongxing Wei , Pengfei Sun
The hollow spherical LaFeO3 perovskite materials were assembled successfully via a templating method and attached calcination treatment. Detailed studies of LaFeO3 perovskites were conducted with regard to their microstructures, morphologies, compositions, and chemical bonding states. The electrochemical performances of hollow spherical LaFeO3 as lithium-ion battery anodes were illustrated. The discharge capacity was 981 mAh g−1 after 200 cycles at the current density of 500 mA g−1, and 316 mAh g−1 could be preserved even after 1000 cycles. The unique perovskite and stable hollow spherical structure not only provide LaFeO3 with improved circulation stability and capacity retention, but also effectively shorten the transport distance of Li+, strengthen the reaction kinetics and expand the electrode/electrolyte interface. In this study, hollow spherical LaFeO3 perovskites were discovered to be reliable candidates for lithium-ion battery anodes.
中文翻译:
空心球状 LaFeO3 钙钛矿作为锂离子电池负极材料
通过模板法和附加煅烧处理成功组装了空心球形LaFeO 3钙钛矿材料。对LaFeO 3钙钛矿的微观结构、形态、组成和化学键合状态进行了详细研究。阐述了空心球形LaFeO 3作为锂离子电池负极的电化学性能。在500 mA g -1 的电流密度下,200次循环后的放电容量为981 mAh g -1,1000次循环后仍能保持316 mAh g -1 。独特的钙钛矿和稳定的空心球结构不仅提供LaFeO 3提高了循环稳定性和容量保持率,同时也有效缩短了Li +的传输距离,加强了反应动力学,扩大了电极/电解质界面。在这项研究中,发现空心球形 LaFeO 3钙钛矿是锂离子电池阳极的可靠候选材料。