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Reactive sulfide dynamic models for predicting metal hazardous in sediments of two northern Egyptian Lakes
Marine Pollution Bulletin ( IF 5.3 ) Pub Date : 2023-02-10 , DOI: 10.1016/j.marpolbul.2023.114694
Gehan M El Zokm 1 , Mamdouh S Masoud 2 , Essam Kh El-Shorbagi 3 , Rehab M I Elsamra 2 , Mohamed A Okbah 1
Affiliation  

To track pollution status and bioavailability of Cu, Zn, Cd, Pb, and Ni, the current study's acid-volatile sulfide (AVS) and simultaneously extracted metals (SEM) models were compared to previous studies in Edku and Mariut lakes prior to 8 years. Sediment samples were collected in winter and summer 2019 from the two lakes. Metal pollution is higher in the winter than in the summer, according to SEM/AVS models. Metal toxicity is reported to have increased slightly in both lakes. According to risk quotients (RQSEM-PEL and RQSEM-TEL) the two lakes are moderately polluted. The results of the Fe/AVS ratio were in the range of 6.77 to 226.87 and 2.88 to 36.38 μmol/g for Edku and Mariut lakes, respectively. This indicated that [SEM]/[AVS] ratios overestimate the availability of metals. A positive correlation was reported between total organic matter and ∑SEM (r = 0.74 and 0.39 at p < 0.05) in Mariut and Edku lakes, respectively. Multiple-year SEM-AVS studies are recommended.



中文翻译:

用于预测埃及北部两个湖泊沉积物中金属危害的反应性硫化物动态模型

为了跟踪 Cu、Zn、Cd、Pb 和 Ni 的污染状况和生物利用度,将当前研究的酸挥发性硫化物 (AVS) 和同时提取的金属 (SEM) 模型与 8 年前在 Edku 和 Mariut 湖中进行的研究进行了比较. 沉积物样本于 2019 年冬季和夏季从这两个湖泊采集。根据 SEM/AVS 模型,冬季金属污染高于夏季。据报道,这两个湖泊的金属毒性略有增加。根据风险商数(RQ SEM-PEL和 RQ SEM-TEL) 两湖均为中度污染。对于 Edku 和 Mariut 湖,Fe/AVS 比率的结果分别在 6.77 至 226.87 和 2.88 至 36.38 μmol/g 的范围内。这表明 [SEM]/[AVS] 比率高估了金属的可用性。在 Mariut 和 Edku 湖中,总有机质与 ∑SEM(r = 0.74 和 0.39,p < 0.05)之间分别报告了正相关性。建议进行多年 SEM-AVS 研究。

更新日期:2023-02-11
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