Selective alkane hydroxylation and alkene epoxidation using H2O2 and Fe(II) catalysts electrostatically attached to a fluorinated surface,Chemical Communications

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Selective alkane hydroxylation and alkene epoxidation using H2O2 and Fe(II) catalysts electrostatically attached to a fluorinated surface
Chemical Communications ( IF 4.3 ) Pub Date : 2023-02-09 , DOI: 10.1039/d2cc06998a
Hiroto Fujisaki ₁ , Masaya Okamura ₂ , Shiro Hikichi _{2,

3} , Takahiko Kojima _{1,

3}

Affiliation

Fe(II) complexes with pentadentate ligands, including N-heterocyclic carbene moieties, were prepared and electrostatically attached onto the perfluorinated surface of a mesoporous aluminosilicate. The heterogeneous catalysts were applied to the catalytic oxidation of cyclohexane and cyclohexene using H₂O₂ as an oxidant in CH₃CN, demonstrating high performance and selectivity in alkane hydroxylation and cyclohexene epoxidation.

中文翻译：

使用静电附着在氟化表面上的 H2O2 和 Fe(II) 催化剂进行选择性烷烃羟基化和烯烃环氧化

制备了具有五齿配体（包括N-杂环卡宾部分）的Fe( II ) 配合物，并将其静电附着在介孔硅铝酸盐的全氟化表面上。将该非均相催化剂应用于以H ₂ O ₂作为氧化剂在CH ₃ CN中催化氧化环己烷和环己烯，在烷烃羟基化和环己烯环氧化中表现出高性能和选择性。

更新日期：2023-02-09

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