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Reactions Involving Multiple Isocyanide Insertions
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2023-02-01 , DOI: 10.1002/adsc.202200995 Zahra Tashrifi 1 , mohammad mohammadi-khanaposhtani 2 , fatemeh gholami 2 , Bagher Larijani 3 , Mohammad Mahdavi 3
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2023-02-01 , DOI: 10.1002/adsc.202200995 Zahra Tashrifi 1 , mohammad mohammadi-khanaposhtani 2 , fatemeh gholami 2 , Bagher Larijani 3 , Mohammad Mahdavi 3
Affiliation
Isocyanides (isonitriles or carbylamine) have been intensively used in organic synthesis to prepare a diverse variety of N-heterocycles on the basis of the carbene-like reactivity of their divalent carbon atom. Isocyanides participate in a variety of reactions involving one, two, or more isocyanides. Compared to the popularity of single isocyanide reactions, few examples of reactions involving two or more isocyanides have been reported. In this review, we categorized and classified the literatures of reactions involving two or more isocyanides especially double isocyanide insertions under metal-catalyzed or metal-free conditions from 2014 to 2022.
中文翻译:
涉及多次异氰化物插入的反应
异氰化物(异腈或甲胺)已广泛用于有机合成,以基于其二价碳原子的卡宾样反应性制备多种多样的 N-杂环。异氰化物参与涉及一种、两种或多种异氰化物的各种反应。与流行的单一异氰化物反应相比,涉及两种或多种异氰化物的反应的例子很少见。在这篇综述中,我们对 2014 年至 2022 年在金属催化或无金属条件下涉及两个或多个异氰化物特别是双异氰化物插入反应的文献进行了分类和分类。
更新日期:2023-02-01
中文翻译:
涉及多次异氰化物插入的反应
异氰化物(异腈或甲胺)已广泛用于有机合成,以基于其二价碳原子的卡宾样反应性制备多种多样的 N-杂环。异氰化物参与涉及一种、两种或多种异氰化物的各种反应。与流行的单一异氰化物反应相比,涉及两种或多种异氰化物的反应的例子很少见。在这篇综述中,我们对 2014 年至 2022 年在金属催化或无金属条件下涉及两个或多个异氰化物特别是双异氰化物插入反应的文献进行了分类和分类。