FeCl2-Catalyzed Rearrangement of Aryl Peroxyoxindole into 1,3-Benzooxazin-4-One,Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

FeCl2-Catalyzed Rearrangement of Aryl Peroxyoxindole into 1,3-Benzooxazin-4-One
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2023-02-01 , DOI: 10.1002/adsc.202201308
Nirmala mohanta ₁ , Pragnya Paramita Samal ₂ , Sailaja Krishnamurty ₂ , Boopathy Gnanaprakasam ₁

Affiliation

We report an FeCl₂-catalyzed radical rearrangement of aryl peroxyoxindoles into 1,3-benzooxazin-2-ones to obtain a variety of aryl substituted 1,3-benzooxazin-4-ones in moderate to good yields. Mechanistically, this skeletal rearrangement of peroxyoxindoles proceeded via radical pathway and was well supported with a series of experimental findings and DFT studies.

中文翻译：

FeCl2 催化芳基过氧吲哚重排为 1,3-苯并恶嗪-4-一

我们报告了 FeCl ₂催化的芳基过氧吲哚自由基重排为 1,3-苯并恶嗪-2-酮，以中等至良好的收率获得各种芳基取代的 1,3-苯并恶嗪-4-酮。从机制上讲，过氧吲哚的这种骨架重排通过自由基途径进行，并得到一系列实验结果和 DFT 研究的充分支持。

更新日期：2023-02-01

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南