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Rigid-Flexible Hybrid Porous Molecular Crystals with Guest-Induced Reversible Crystallinity
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-01-31 , DOI: 10.1002/anie.202217903 Danbo Wang 1 , Yingjie Zhao 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-01-31 , DOI: 10.1002/anie.202217903 Danbo Wang 1 , Yingjie Zhao 1
Affiliation
A globally robust HOF with both rigidity and flexibility was constructed. The non-crystalline and crystalline phases of the HOF could be easily and reversibly switched at will with the specific solvent molecule. Furthermore, the obtained HOF exhibits excellent separation efficiency for benzene and cyclohexane (94.4 %).
中文翻译:
具有客体诱导可逆结晶性的刚柔杂化多孔分子晶体
构建了具有刚性和灵活性的全局鲁棒 HOF。HOF 的非结晶相和结晶相可以通过特定的溶剂分子轻松、可逆地任意转换。此外,所获得的 HOF 对苯和环己烷表现出优异的分离效率 (94.4%)。
更新日期:2023-01-31
中文翻译:
具有客体诱导可逆结晶性的刚柔杂化多孔分子晶体
构建了具有刚性和灵活性的全局鲁棒 HOF。HOF 的非结晶相和结晶相可以通过特定的溶剂分子轻松、可逆地任意转换。此外,所获得的 HOF 对苯和环己烷表现出优异的分离效率 (94.4%)。