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Luminous lanthanide diketonates: Review on synthesis and optoelectronic characterizations
Inorganica Chimica Acta Pub Date : 2023-01-28 , DOI: 10.1016/j.ica.2023.121406
Anuj Dalal , Kapeesha Nehra , Anjli Hooda , Devender Singh , Parvin Kumar , Sumit Kumar , Rajender Singh Malik , Brijesh Rathi

Lanthanide metal complexes with light-harvesting organic chromophoric moieties have gained extensive interest in the past decade owing to their outstanding performance in a variety of technological sectors. Organic compounds for sensitizing the luminescence in lanthanides are being studied to promote the production of new lanthanide compounds. Lanthanide complexes are good materials for solid state lighting and electroluminescent displays because of their well emission characteristics, fine color range, and large quantum efficiency. These ternary complexes are widely employed in the production of optoelectronic devices. This review comprises the various methods to synthesize lanthanides (Eu(III), Sm(III) and Tb(III)) β-diketonate complexes with 2,2′-bipyridine {bpy} and 1,10-phenanthroline {phen}, as well as their derivatives. Eu(III) complexes emit red, Sm(III) complexes emit orange while Tb(III) complexes emit green color. The characterization of these complexes is done by different techniques i.e. elemental analysis, infra-red (IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, mass spectrometry, ultraviolet spectroscopy, photoluminescence spectroscopy, X-ray diffraction, thermogravimetric, and electrochemical analyses.



中文翻译:

发光的镧系元素二酮酸盐:合成和光电表征综述

具有光捕获有机发色团部分的镧系金属配合物在过去十年中因其在各种技术领域的出色表现而受到广泛关注。正在研究用于敏化镧系元素发光的有机化合物以促进新镧系元素化合物的产生。镧系元素配合物是用于固态照明和电致发光显示器的良好材料,因为它们具有良好的发射特性、精细的颜色范围和大的量子效率。这些三元配合物广泛用于光电器件的生产。本综述包括用 2,2'-联吡啶 {bpy} 和 1,10-菲咯啉 {phen} 合成镧系元素(Eu(III)、Sm(III) 和 Tb(III))β-二酮络合物的各种方法,如以及它们的衍生物。Eu(III) 配合物发出红色,Sm(III) 配合物发出橙色,而 Tb(III) 配合物发出绿色。这些配合物的表征是通过不同的技术完成的元素分析、红外 (IR) 光谱、核磁共振 (NMR) 光谱、质谱、紫外光谱、光致发光光谱、X 射线衍射、热重分析和电化学分析。

更新日期:2023-01-28
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