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Polarity-Evolution Control and Luminescence Regulation in Multiple-Site Hydrogen-Bonded Organic Frameworks
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-01-27 , DOI: 10.1002/chem.202204045
Yuanchao Lv 1 , Jiashuai Liang 1 , Zhile Xiong 1 , Hao Zhang 1 , Delin Li 1 , Xue Yang 1 , Shengchang Xiang 1 , Zhangjing Zhang 1
Affiliation  

The solvent-polarity effect on the framework/luminescence regulation was demonstrated based on the multiple-site hydrogen-bonded organic frameworks: distinct electrostatic forces controlled by solvent polarities (high/low) would benefit for the different framework (cage/channel) structures; the solvent polarity could further adjust the conformation of organic building unit to generate a broadband tunable luminescence.

中文翻译:

多位点氢键有机骨架中的极性演变控制和发光调节

基于多位点氢键有机框架证明了溶剂极性对框架/发光调节的影响:由溶剂极性(高/低)控制的不同静电力将有利于不同的框架(笼/通道)结构溶剂的极性可以进一步调整有机结构单元的构象,从而产生宽带可调谐发光。
更新日期:2023-01-27
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