Optical Materials ( IF 3.8 ) Pub Date : 2023-01-27 , DOI: 10.1016/j.optmat.2023.113515 Shuo Huang , Liang Wang , Mei Lyu , Junxi Zhang , Jun Zhu
In recent years, amplified spontaneous emission (ASE) properties of all-inorganic perovskite quantum dots have attracted the interest of many researchers. Here, CsPbI2Br quantum dots (QDs) were synthesized by the hot injection method, and the effect of the purification process on the ASE properties of QDs has been investigated. In the purification process, n-hexane and ethyl acetate (EtOAc) are used as solvent and antisolvent, respectively. The results show that the volume ratio of n-hexane vs EtOAc has a remarkable effect on the optical performance. When the volume ratio is 1:5, the QDs have a larger size which increases the light scattering and absorption cross-section, thus achieving the lowest ASE threshold of 0.301 mJ/cm2. This work not only provides a facile strategy to obtain a low threshold of CsPbI2Br QDs but also enriches the application prospects of perovskite lasers.
中文翻译:
表面配体密度对CsPbI2Br量子点放大自发辐射特性的影响
近年来,全无机钙钛矿量子点的放大自发辐射(ASE)特性引起了许多研究人员的兴趣。在这里,通过热注入法合成了CsPbI 2 Br 量子点 (QD),并研究了纯化过程对 QD 的 ASE 特性的影响。在纯化过程中,正己烷和乙酸乙酯(EtOAc)分别用作溶剂和反溶剂。结果表明,正己烷与EtOAc的体积比对光学性能有显着影响。当体积比为1:5时,量子点具有更大的尺寸,增加了光散射和吸收截面,从而实现0.301 mJ/cm 2的最低ASE阈值. 这项工作不仅为获得低阈值的 CsPbI 2 Br QD 提供了一种简便的策略,而且丰富了钙钛矿激光器的应用前景。