Halide Layer Cathodes for Compatible and Fast-Charged Halides-Based All-Solid-State Li Metal Batteries,Angewandte Chemie International Edition

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Halide Layer Cathodes for Compatible and Fast-Charged Halides-Based All-Solid-State Li Metal Batteries
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-01-25 , DOI: 10.1002/anie.202217081
Jianwen Liang ₁ , Xiaona Li ₁ , Jung Tae Kim ₁ , Xiaoge Hao ₁ , Hui Duan ₁ , Ruying Li ₁ , Xueliang Sun ₁

Affiliation

A lithium intercalation chemistry in layered VX₃ (X=Cl, Br, I) enabled by compatible halide-based solid electrolytes was explored for the first time. The electrode-electrolyte interfacial stability can be achieved in a thermodynamic manner instead of by passivation, ensured by the good chemical stability between the VX₃ cathode and halide electrolytes as well as the wide electrochemical stability windows.

中文翻译：

用于兼容和快速充电的卤化物基全固态锂金属电池的卤化物层阴极

首次探索了由兼容的卤化物基固体电解质实现的层状 VX ₃ (X=Cl, Br, I)中的锂嵌入化学。电极-电解质界面稳定性可以通过热力学方式而不是通过钝化来实现，由 VX ₃阴极和卤化物电解质之间良好的化学稳定性以及宽的电化学稳定性窗口确保。

更新日期：2023-01-25

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