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A new Schiff base derived from 5-(thiophene-2-yl)oxazole as “off-on-off” fluorescence sensor for monitoring indium and ferric ions sequentially and its application
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.3 ) Pub Date : 2023-01-18 , DOI: 10.1016/j.saa.2023.122376
Yuanying Liu 1 , Huanxia Cui 2 , Kehui Wei 1 , Mingyi Kang 1 , Peng Liu 1 , Xiaofeng Yang 1 , Meishan Pei 1 , Guangyou Zhang 1
Affiliation  

A new Schiff base sensor (E)-N'-((8-hydroxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolin-9-yl)methylene)-5-(thiophen-2-yl)oxazole-4-carbohydrazide (TOQ) was synthesized and found to emit yellowish green fluorescence upon introduction of In3+. Furthermore, the resulting complex TOQ-In3+ was quenched selectively by Fe3+. The detection limits of TOQ for In3+ and Fe3+ were 1.75 × 10-10 M and 8.45 × 10-9 M, respectively. The complex stoichiometry of TOQ with target ions was determined to be 1:2 via Job’s plot analysis, which further was verified by ESI-MS titration and theoretical calculations. Moreover, TOQ can be used for the determination of target ions in environmental water samples. A portable paper sensor of TOQ was successfully developed for detecting In3+ to assess its applicability.



中文翻译:

5-(噻吩-2-基)恶唑衍生的新型席夫碱“关-关-关”荧光传感器连续监测铟铁离子及其应用

新型席夫碱传感器 ( E )- N' -((8-hydroxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1- ij ]quinolin-9-yl)methylene)合成了-5-(thiophen-2-yl)oxazole-4-carbohydrazide ( TOQ ),发现在引入 In 3+时会发出黄绿色荧光。此外,生成的复合物TOQ -In 3+被 Fe 3+选择性淬灭。In 3+和Fe 3+的TOQ检测限分别为1.75 × 10 -10 M 和8.45 × 10 -9 M。TOQ的复杂化学计量通过 Job's plot 分析确定与目标离子的比例为 1:2,并通过 ESI-MS 滴定和理论计算进一步验证。此外,TOQ可用于测定环境水样中的目标离子。成功开发了用于检测 In 3+的TOQ便携式纸张传感器,以评估其适用性。

更新日期:2023-01-18
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