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C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O: An Unprecedented Asymmetric Guanidinium Polyiodate with a Strong Second-Harmonic-Generation Response and a Wide Band Gap
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2023-01-19 , DOI: 10.1021/acs.inorgchem.3c00002 Dong Yan 1, 2 , Meng-Meng Ren 1 , Fei-Fei Mao 2, 3 , Yu Ma 2 , Ru-Ling Tang 4 , Bingbing Zhang 5 , Yao Ma 1 , Xiu-Du Zhang 1 , Shu-Fang Li 1, 2
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2023-01-19 , DOI: 10.1021/acs.inorgchem.3c00002 Dong Yan 1, 2 , Meng-Meng Ren 1 , Fei-Fei Mao 2, 3 , Yu Ma 2 , Ru-Ling Tang 4 , Bingbing Zhang 5 , Yao Ma 1 , Xiu-Du Zhang 1 , Shu-Fang Li 1, 2
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Herein, we report an unprecedented asymmetric guanidinium polyiodate, namely, C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O (1). The title compound was obtained via the hybridization of polyiodate anions and planar π-conjugated C(NH2)3+; meanwhile, its strong second-harmonic-generation (SHG) response (2.1 × KDP, where KDP = KH2PO4) and wide band gap (3.89 eV) were mainly dominated by the synergy effect of the aforementioned structural units.
中文翻译：
C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O：前所未有的不对称聚碘酸胍，具有强二次谐波产生响应和宽带隙
在此，我们报道了一种前所未有的不对称多碘酸胍，即 C(NH 2 ) 3 (I 3 O 8 )(HI 3 O 8 )(H 2 I 2 O 6 )(HIO 3 ) 4 ·3H 2 O ( 1 ) . 标题化合物通过多碘酸阴离子和平面π-共轭C(NH 2 ) 3 +的杂化获得；同时，其强大的二次谐波产生 (SHG) 响应 (2.1 × KDP，其中 KDP = KH 2 PO 4) 和宽带隙 (3.89 eV) 主要受上述结构单元的协同效应支配。
更新日期：2023-01-19
中文翻译：
C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O：前所未有的不对称聚碘酸胍，具有强二次谐波产生响应和宽带隙
在此，我们报道了一种前所未有的不对称多碘酸胍，即 C(NH 2 ) 3 (I 3 O 8 )(HI 3 O 8 )(H 2 I 2 O 6 )(HIO 3 ) 4 ·3H 2 O ( 1 ) . 标题化合物通过多碘酸阴离子和平面π-共轭C(NH 2 ) 3 +的杂化获得；同时，其强大的二次谐波产生 (SHG) 响应 (2.1 × KDP，其中 KDP = KH 2 PO 4) 和宽带隙 (3.89 eV) 主要受上述结构单元的协同效应支配。
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