1,2-BN Cyclohexane: Synthesis, Structure, Dynamics, and Reactivity,Journal of the American Chemical Society

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1,2-BN Cyclohexane: Synthesis, Structure, Dynamics, and Reactivity
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2011-08-24 , DOI: 10.1021/ja206497x
Wei Luo ₁ , Lev N. Zakharov ₁ , Shih-Yuan Liu ₁

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BN/CC isosterism has emerged as a viable strategy to increase the structural diversity of carbon-based compounds. We present the first synthesis and characterization of the parent 1,2-BN cyclohexane, the BN-isostere of cyclohexane. 1,2-BN cyclohexane is an air- and water-stable compound that cleanly forms a trimer with release of dihydrogen when thermally activated. We also demonstrate that 1,2-BN cyclohexane has a lower activation barrier for ring inversion than cyclohexane due to BN/CC isosterism.

中文翻译：

1,2-BN 环己烷：合成、结构、动力学和反应性

BN/CC 等排结构已成为增加碳基化合物结构多样性的可行策略。我们首次合成和表征了母体 1,2-BN 环己烷，即环己烷的 BN 等排体。1,2-BN 环己烷是一种空气和水稳定的化合物，当热活化时，它会干净地形成三聚体并释放二氢。我们还证明，由于 BN/CC 等排效应，1,2-BN 环己烷比环己烷具有更低的环反转激活势垒。

更新日期：2011-08-24

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