Discovery of (E)-2-Methoxyethene-1-sulfonyl Fluoride for the Construction of Enaminyl Sulfonyl Fluoride,The Journal of Organic Chemistry

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Discovery of (E)-2-Methoxyethene-1-sulfonyl Fluoride for the Construction of Enaminyl Sulfonyl Fluoride
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2023-01-17 , DOI: 10.1021/acs.joc.2c02836
Min Liu ₁ , Wenjian Tang ₂ , Hua-Li Qin ₁

Affiliation

A new sulfonyl fluoride reagent (E)-2-methoxyethene-1-sulfonyl fluoride (MeO-ESF) was developed and successfully applied for the construction of enaminyl sulfonyl fluoride (N-ESF). This protocol provides highly atom-economical access to diverse N-ESF and produces CH₃OH as the sole byproduct under mild and environmentally benign conditions.

中文翻译：

发现 (E)-2-Methoxyethene-1-sulfonyl Fluoride 用于构建烯胺基磺酰氟

开发了一种新型磺酰氟试剂( E )-2-甲氧基乙烯-1-磺酰氟(MeO-ESF)，并成功应用于构建烯胺基磺酰氟( N -ESF )。该协议提供了对不同N -ESF 的高度原子经济访问，并在温和和环境友好的条件下产生 CH _{3 OH 作为唯一的副产品。}

更新日期：2023-01-17

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