Spectroscopic Identification of Diphosphene HPPH and Isomeric Diphosphinyldene PPH2,Angewandte Chemie International Edition

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Spectroscopic Identification of Diphosphene HPPH and Isomeric Diphosphinyldene PPH2
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-01-13 , DOI: 10.1002/anie.202217353
Bo Lu ₁ , Lina Wang ₁ , Xin Jiang ₁ , Guntram Rauhut ₂ , Xiaoqing Zeng ₁

Affiliation

The simplest diphosphene HPPH (cis and trans conformers) and diphosphinyldene PPH₂ have been generated and spectroscopically characterized in solid N₂- and Ar-matrices at 10 K. In addition to the photo-induced conversion of these P₂H₂ isomers, the prototype phosphorus-phosphorus multiple bonding properties have been disclosed.

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