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Nonlinear Optical Switching Driven by the Lone Pair Electron Effect in a Hybrid Compound: (1S, 4S)-(+)-2-Aza-5-oxabicyclo[2.2.1] heptane)2[SbCl5]
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2023-01-11 , DOI: 10.1002/ejic.202200740 Zhen An 1 , Rong‐Meng Liao 1 , Hai‐Quan Yao 1 , Yan Cheng 1 , Bing‐Jun Zhu 1 , Jian‐Rong Li 1 , Heng‐Yun Ye 1
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2023-01-11 , DOI: 10.1002/ejic.202200740 Zhen An 1 , Rong‐Meng Liao 1 , Hai‐Quan Yao 1 , Yan Cheng 1 , Bing‐Jun Zhu 1 , Jian‐Rong Li 1 , Heng‐Yun Ye 1
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A chiral organic-inorganic hybrid compound (1S, 4S)-(+)-2-Aza-5-oxabicyclo[2.2.1]heptane)2[SbCl5] was constructed and found to show SHG switching effect at transition temperature 382 K. The SHG switching effect is due to the coordination distortion caused by the lone pair electron effect. This finding reveals that the lone pair electron effect might be an effective element in the synthesis of polar hybrid materials.
中文翻译：
杂化化合物中孤对电子效应驱动的非线性光开关：(1S, 4S)-(+)-2-Aza-5-oxabicyclo[2.2.1] heptane)2[SbCl5]
构建了手性有机-无机杂化化合物 (1S, 4S)-(+)-2-Aza-5-oxabicyclo[2.2.1]heptane) 2 [SbCl 5 ] 并发现在转变温度 382 K 时显示出 SHG 开关效应SHG开关效应是由于孤对电子效应引起的配位畸变。这一发现表明，孤对电子效应可能是合成极性杂化材料的有效元素。
更新日期：2023-01-11
中文翻译：
杂化化合物中孤对电子效应驱动的非线性光开关：(1S, 4S)-(+)-2-Aza-5-oxabicyclo[2.2.1] heptane)2[SbCl5]
构建了手性有机-无机杂化化合物 (1S, 4S)-(+)-2-Aza-5-oxabicyclo[2.2.1]heptane) 2 [SbCl 5 ] 并发现在转变温度 382 K 时显示出 SHG 开关效应SHG开关效应是由于孤对电子效应引起的配位畸变。这一发现表明，孤对电子效应可能是合成极性杂化材料的有效元素。
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