Multistate Structural Switching of [3]Catenanes with Cyclic Porphyrin Dimers by Complexation with Amine Ligands,Angewandte Chemie International Edition

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Multistate Structural Switching of [3]Catenanes with Cyclic Porphyrin Dimers by Complexation with Amine Ligands
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-01-10 , DOI: 10.1002/anie.202217002
Yuki Oka ₁ , Hiroshi Masai _{1,

2} , Jun Terao ₁

Affiliation

A ligand-controlled switching method has been developed for the multistate switching of catenanes. To verify this concept, a [3]catenane composed of three macrocyclic metalloporphyrin dimers with a rigid π-backbone was synthesized. Multistate switching of the [3]catenane was achieved by complexation with various amine ligands, with the multistate switching behavior arising from the tunable optical properties of the [3]catenane.

中文翻译：

[3] 环卟啉二聚体与胺配体络合的多态结构转换

已经开发了一种配体控制的切换方法用于链烷的多态切换。为了验证这一概念，合成了由三个具有刚性 π 主链的大环金属卟啉二聚体组成的 [3] 链烷。[3] 链烷的多态转换是通过与各种胺配体络合实现的，多态转换行为是由 [3] 链烷的可调光学特性引起的。

更新日期：2023-01-10

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